• 姓       名:李筱芳
  • 职       称:教授
  • 学       位:博士
  • 所在机构:湖南科技大学 化学化工学院
  • 出生年月: 1972年12月
  • 籍       贯:
  • 研究方向:基于富勒烯;内嵌金属富勒烯;卟啉等大∏-共轭体系的光电功能材料的合成及性质
个人简介 学术成果 发表论文

教育背景

2001年硕士毕业于湖南大学;

2004年博士毕业于天津大学。

工作经历

2004-2006年在中国科学院化学研究所从事博士后研究工作;

2006-2008年在香港科技大学化学系从事研究助理工作;

2015-2016年在波兰弗罗茨瓦夫大学化学系做访问学者。


主持国家自然科学基金3项,教育部科学技术研究重点项目1项,湖南省高等学校科学研究青年项目1项。已发表SCI论文数十篇。

科研项目

[1]反芳香norcorrole衍生物的合成及其在锂离子电池正极材料中的应用(21671063),32.5万元,201701-202012

[2]构型可调的N-错位卟啉及其手性金属配合物的合成及其与G-四链体DNA 的相互作用研究(21371054),80.0万元,201401-201712

[3]基于内嵌金属富勒烯的新功能材料的合成、表征及应用研究(20971041),33.0万元,201001-201212

论文专著

[1]1,3-dipolar cycloaddition of 2,6-dichlorobenzonitrile oxide to 2-methyl-N-confused porphyrin. regio- and stereoselective synthesis and structural characterization of 2-Aza-21-carbabacteriochlorin and resolution of 2-Aza-21-carbachlorin enantiomers,J. Org. Chem. 2012, 77, 5, 2431-2440

[2]Synthesis of novel spiro thiazolotriazole derivatives via 1,3-dipolar cycloaddition of azomethine ylide, J. Heterocyclic Chem. 2012, 49, 5, 1050-1053

[3]Synthesis of dispiro[indole-3,2-pyrrolidine-3’,2''-pyrrolizine]-1'',2(1H)-diones via azomethine ylide 1,3-dipolar cycloaddition, J. Heterocyclic. Chem. 2013, 50, 4, 925-928

[4]Synthesis of a novel triheterocyclic framework via 1,3-dipolar cycloaddition of a nitrile oxide with imidazo[2,1-b][1,3]thiazole-3(2H)-ones, J. Heterocyclic Chem. 2013, 50, 5, 1198-1201

[5]One-pot synthesis of novel spiro pyrano[2,3-d][1,3]thiazolo[3,2-a]pyrimidine derivatives , Synthetic Commun. 2014, 44, 10, 1414-1421

[6]Synthesis of new spiro isoxazoline-pyrrolizinone derivatives via 1,3-dipolar cycloaddition of nitrile oxide, J. Heterocyclic Chem. 2014, 51, 1, 274-276

[7]3(dialkoxyphosphoryl)-N-confused phlorin and porphyrin. synthesis, stereochemistry, and coordination properties, J. Org. Chem. 2013, 78, 4, 1354-1364

[8]L-proline catalyzed reaction of N-confused porphyrin and active methylene compounds, Org. Biomol. Chem. 2013, 11, 4831-4839

[9]Synthesis of novel spiro pyrano[2,3-d]thiazolo[3,2‐a]pyrimidine via 1,3-dipolar cycloaddition of azomethine ylide, J. Heterocyclic Chem. 2013, 50, 5, 1009-1013

[10]Synthesis of novel dispiro[acenaphthylene-pyrrolidine-pyrrolisine] derivatives via a 1,3-dipolar cycloaddition of azomethine ylide, J. Chem. Res. 2013, 37, 12, 715-782

[11]Unexpected nitrilimine cycloaddition of thiazolo[3,2-a]pyrimidine derivatives, Tetrahedron Lett. 2013, 54, 50, 6952-6954

[12]Synthesis of novel spiro[cyclopropane-indolizine] derivatives via magnesium-mediated conjugate addition of bromoform, J. Chem. Res. 2013, 37, 11, 649-714

[13]Regioselective internal carbonylation of the 2 Aza-21- carbaporphyrin: access to configurationally stable chiral porphyrinoids, J. Org. Chem. 2014, 79, 7, 3129-3139

[14]Performance enhancement of inverted polymer solar cells with fullerene ester derivant-modified ZnO film as cathode buffer layer, Sol. Energ. Mat. Sol. C 2014, 126, 36-41

[15]Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc3N@Ih-C80 affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes, Chem. Commun. 2014, 50, 84, 12710-12713

[16]Synthesis and photophysical properties of a Sc3N@C80-corrole electron donor–acceptor conjugate, Chem-Eur. J. 2015, 21, 2, 746-752

[17]Synthesis of novel spiro[oxirane-pyrrolizin] derivatives by epoxidation of α,β-unsaturated pyrrolizinone with cyclohexylidenebishydroperoxide, J. Chem. Res. 2015, 39, 10, 555-560

[18]Synthesis of novel spiro[cyclopropane-pyrrolizin] derivatives via Mg-mediated conjugate addition of bromoform, Res. Chem. Intermediat. 2015, 41, 2345

[19]Towards norcorrin: hydrogenation chemistry and the heterodimerization of nickel(II) norcorrole, Chem-Eur. J. 2015, 21, 21, 7790-7797

[20]Synthesis of tetrahydrothiophene and thiophene-fused porphyrin, Chem. Lett. 2015, 44, 11, 1515-1517

[21] Nitration of norcorrolatonickel(II): first observation of a diatropic current in a dystem comprising a norcorrole ring, Chem-Eur. J. 2016, 22, 12, 4231-4246

[22]Simple and efficient synthesis of pyrazole-fused porphyrins, Tetrahedron Lett, 2016, 57, 1265-1267

[23]Reversible Carbon–Carbon Bond Breaking and Spin Equilibria in Bis(pyrimidinenorcorrole), Angew. Chem. Int. Ed. 2016, 55, 13142 –13146

[24]Pyridine-Fused Bis(Norcorrole) through Hantzsch-Type Cyclization: Enhancement of Antiaromaticity by an Aromatic Bridge , Angew.Chem.Int. Ed. 2017, 56,10810 –10814