• 姓       名:曹书霞
  • 职       称:教授
  • 学       位:博士
  • 所在机构:郑州大学 化学与分子工程学院
  • 出生年月:
  • 籍       贯:
  • 研究方向:有机波谱学;有机磷化学
个人简介 学术成果 发表论文

教育背景

1990年获郑州大学理学学士学位;

1993年获郑州大学理学硕士学位;

2004年获郑州大学理学博士学位。

工作经历

1993-1996 年 郑州大学化学系助教;

1996-2004年 郑州大学化学系讲师;

2004-2009年 郑州大学化学系副教授;

2006-2007年英国牛津大学化学系,国家公派访问学者;

2009-至今 郑州大学化学与分子工程学院教授。

科研项目

1.2005.7-2007.7,“环肽及其衍生物的合成与生物活性研究”,编号200510459015,河南省自然科学基金:基础研究项目;

2.2007.1-2009.12,“磷试剂辅助环肽的模版合成及其超分子识别作用研究”,编号:20672104,国家自然科学基金项目;

3.2011.1-2013.10,“双分子氨基酸氢膦烷的合成及其反应活性研究”,编号:2011A150028,河南省自然科学基金:基础研究项目;

4.2012.1–2015.12,“磷中心手性氨基酸螺环氢膦烷的类Atherton-Todd反应研究”,编号:21172201,国家自然科学基金项目。

论文专著

ShuxiaCao*,PengGao,YanchunGuo,HuaminZhao,JunWang,YifanLiu,YufenZhao,UnexpectedinsertionofCO2intothepentacoordinateP–NBond:Atherton–Todd-typereactionofhydrospirophosphoranewithamines,J.Org.Chem.,2013,78(22),11283–11293.

ShuxiaCao*,YanchunGuo,JunWang,LinQi,PengGao,HuaminZhao,YufenZhao,PreliminarystereochemicalinvestigationoftheAtherton-Todd-typereactionbetweenvalinehydrospirophosphoraneandphenols,TetrahedronLetters,2012,53,6302-6305.

ShuxiaCao*,YanchunGuo,XinshuaiWu,HuaminZhao,YufenZhao*,Fragmentationstudiesofpentacoordinatedbisaminoacylspirophosphoranesbynegativeelectrosprayionizationmassspectrometry,JournalofMassSpectrometry,2011,46,352-358.

YanchunGuo,ShuxiaCao*,YaliXie,XiangkunZong,YufenZhao*,InvestigationofReactionMechanismofAminoAcidsandPhosphorusTrichlorideby31PNMRandESI-MS/MS,ChineseJournalofChemistry,2011,29,1173-1179.

JihongLiu,ShuxiaCao*,ZhipingZeng,XinchengLiao,JianshaLu,YufenZhao*,TheInvestigationofInteractionCompetitionbetweenATPandDIPP-Ala,Boc-AlaorAlabyESI-MS/MSandTheoreticalCalculation,Phosphorus,Sulfur,andSilicon,2010,185,1587-1593.

YanchunGuo,ShuxiaCao*,DonghuiWei1,XiangkunZong,XingboYuan,MingshengTang,YufenZhao*,Fragmentationofdeprotonatedcyclicdipeptidesbyelectrosprayionizationmassspectrometry,JournalofMassSpectrometry,2009,44,1188-1194.

JihongLiu,ShuxiaCao*,BinJia,DonghuiWei,XinchengLiao,JianshaLu,YufenZhao*,ATheoreticalandMassSpectrometryStudyoftheNovelMechanismofN-glycosidicBondCleavageinNucleoside,InternationalJournalofMassSpectrometry,2009,282(1-2),1-5.

YanchunGuo,ShuxiaCao*,XiangkunZong,XinchengLiao,YufenZhao*,ESI-MSnstudyonthefragmentationofprotonatedcyclic-dipeptides,Spectroscopy,2009,23(3,4),131-139.

LimingQiang,RuoyuLiu,YaliXie,ShuxiaCao*,XinchengLiao,YufenZhao*.AcarbonyloxygenmigrationofN-phosphoryldipeptidemethylesterscontainingβ-alanineorγ-aminobutyricacidinelectrosprayionizationmassspectrometry,InternationalJournalofMassSpectrometry,2008,272,204-207.

ShuxiaCao,HongminLiu,WenXu,XinchengLiao,YufenZhao*,Characterizingtheelectrospray-ionizationmassspectralfragmentationpatternofindolederivativessynthesizedfrom2-ketoglycosides,JournalofMassSpectrometry,2005,40(4),452-457.

ShuxiaCao,YuqianSu,XiaoliYang,XiaolanChen,YufenZhao*,TheInvestigationofβ-CyclodextrinNoncovalentComplexwithProteinorDipeptidebyElectrosprayIonizationMassSpectrometry,AnalyticalLetters,2004,37(09),1871-1883.

ShuxiaCao,JianchenZhang,JunXu,XinchengLiao,YufenZhao*,AnalysisofHydrolysisReactionofN-PhosphorylPhenylalaninebyHPLC-ESI-MS/MS,ChineseChemicalLetters,2004,15(7),817-820.

ShuxiaCao,JianchenZhang,JunXu,XinchengLiaoandYufenZhao*,ElectrosprayTandemMassSpectrometricStudiesofalltwentyN-phosphorylAminoAcids,RapidCommunicationsinMassSpectrometry,2003,17(19),2237-2240.

ShuxiaCao,YuqianSu,JianchenZhang,HongxiaLiu,YufenZhao*,CharacterizationofN-phosphoryloligopeptidelibrariesbyESI-MSandHPLC-MS,LetterinPeptideScience,2003,10(5-6),631-635.

奖励/荣誉

获郑州大学青年骨干教师荣誉称号; 

获郑州大学中青年教师讲课大赛二等奖;

获郑州市科技进步二等奖1项;

获河南省优秀科技论文奖8项。